Selective photocatalytic oxidation of aromatic alcohols to aldehydes in an aqueous suspension of gold nanoparticles supported on cerium(IV) oxide under irradiation of green light

被引:114
作者
Tanaka, Atsuhiro [1 ]
Hashimoto, Keiji [1 ]
Kominami, Hiroshi [1 ]
机构
[1] Kinki Univ, Dept Appl Chem, Fac Sci & Engn, Osaka 5778502, Japan
关键词
AEROBIC OXIDATION; TITANIUM-DIOXIDE; CORRESPONDING ALDEHYDES; BENZYLIC ALCOHOLS; MOLECULAR-OXYGEN; CATALYST; TIO2; WATER; EFFICIENT; CLUSTERS;
D O I
10.1039/c1cc13801d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold nanoparticles supported on cerium(IV) oxide powder showing strong absorption at around 550 nm due to surface plasmon resonance oxidized aromatic alcohols to corresponding aldehydes almost quantitatively in an aqueous suspension under irradiation of green light.
引用
收藏
页码:10446 / 10448
页数:3
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共 30 条
[1]   Unique gold chemoselectivity for the aerobic oxidation of allylic alcohols [J].
Abad, Alberto ;
Almela, Carles ;
Corma, Avelino ;
Garcia, Hermenegildo .
CHEMICAL COMMUNICATIONS, 2006, (30) :3178-3180
[2]   Aerobic Oxidation of Benzylic Alcohols Catalyzed by Metal-Organic Frameworks Assisted by TEMPO [J].
Dhakshinamoorthy, Amarajothi ;
Alvaro, Mercedes ;
Garcia, Hermenegildo .
ACS CATALYSIS, 2011, 1 (01) :48-53
[3]   Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts [J].
Enache, DI ;
Edwards, JK ;
Landon, P ;
Solsona-Espriu, B ;
Carley, AF ;
Herzing, AA ;
Watanabe, M ;
Kiely, CJ ;
Knight, DW ;
Hutchings, GJ .
SCIENCE, 2006, 311 (5759) :362-365
[4]   Aerobic Oxidation of Benzylic Alcohols in Water by 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO)/Copper(II) 2-N-Arylpyrrolecarbaldimino Complexes [J].
Figiel, Pawel J. ;
Sibaouih, Ahlam ;
Ahmad, Jahir Uddin ;
Nieger, Martin ;
Raisanen, Minna T. ;
Leskela, Markku ;
Repo, Timo .
ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (16) :2625-2632
[5]   HETEROGENEOUS PHOTOCATALYSIS [J].
FOX, MA ;
DULAY, MT .
CHEMICAL REVIEWS, 1993, 93 (01) :341-357
[6]   Ultrafast plasmon-induced electron transfer from gold nanodots into TiO2 nanoparticles [J].
Furube, Akihiro ;
Du, Luchao ;
Hara, Kohjiro ;
Katoh, Ryuzi ;
Tachiya, Masanori .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (48) :14852-+
[7]   Efficient and selective oxidation of benzylic alcohol by O2 into corresponding aldehydes on a TiO2 photocatalyst under visible light irradiation: Effect of phenyl-ring substitution on the photocatalytic activity [J].
Higashimoto, Shinya ;
Suetsugu, Nobuaki ;
Azuma, Masashi ;
Ohue, Hiroyoshi ;
Sakata, Yoshihisa .
JOURNAL OF CATALYSIS, 2010, 274 (01) :76-83
[8]   Effect of Surface Treatment on the Selective Photocatalytic Oxidation of Benzyl Alcohol into Benzaldehyde by O2 on TiO2 Under Visible Light [J].
Higashimoto, Shinya ;
Okada, Kohei ;
Morisugi, Tomoki ;
Azuma, Masashi ;
Ohue, Hiroyoshi ;
Kim, Tae-Ho ;
Matsuoka, Masaya ;
Anpo, Masakazu .
TOPICS IN CATALYSIS, 2010, 53 (7-10) :578-583
[9]   Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation [J].
Higashimoto, Shinya ;
Kitao, Naoya ;
Yoshida, Norio ;
Sakura, Teruki ;
Azuma, Masashi ;
Ohue, Hiroyoshi ;
Sakata, Yoshihisa .
JOURNAL OF CATALYSIS, 2009, 266 (02) :279-285
[10]   ENVIRONMENTAL APPLICATIONS OF SEMICONDUCTOR PHOTOCATALYSIS [J].
HOFFMANN, MR ;
MARTIN, ST ;
CHOI, WY ;
BAHNEMANN, DW .
CHEMICAL REVIEWS, 1995, 95 (01) :69-96