Synthesis and characterization of single-crystalline α-MoO3 nanofibers for enhanced Li-ion intercalation applications

被引：96

作者：

Dewangan, Khemchand ^{[2
]}

Sinha, Nupur Nikkan ^{[1
]}

Sharma, Prashant K. ^{[3
]}

Pandey, Avinash C. ^{[3
]}

Munichandraiah, N. ^{[1
]}

Gajbhiye, N. S. ^{[2
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

[2] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

[3] Univ Allahabad, Nanophosphor Applicat Ctr, Allahabad 211002, Uttar Pradesh, India

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 03期

关键词：

MOLYBDENUM; MOO3; NANOSTRUCTURES; NANOPLATELETS; HYDROXYLAMINE; COMPLEXES; NANOBELTS; INSERTION; NANORODS; FIBERS;

D O I：

10.1039/c0ce00271b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High quality, single-crystalline alpha-MoO3 nanofibers are synthesized by rapid hydrothermal method using a polymeric nitrosyl-complex of molybdenum(II) as molybdenum source without employing catalysts, surfactants, or templates. The possible reaction pathway is decomposition and oxidation of the complex to the polymolybdate and then surface condensation on the energetically favorable [001] direction in the initially formed nuclei of solid alpha-MoO3 under hydrothermal conditions. Highly crystalline alpha-MoO3 nanofibers have grown along [001] with lengths up to several micrometres and widths ranging between 280 and 320 nm. The alpha-MoO3 nanofibers exhibit desirable electrochemical properties such as high capacity reversibility as a cathode material of a Li-ion battery.

引用

页码：927 / 933

页数：7

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