A lumped parameter model to predict hydrochloric acid recovery in diffusion dialysis

被引:54
作者
Kang, MS [1 ]
Yoo, KS [1 ]
Oh, SJ [1 ]
Moon, SH [1 ]
机构
[1] Kwangju Inst Sci & Technol, Dept Environm Engn, Kwangju, South Korea
关键词
diffusion dialysis; anion-exchange membrane; hydrochloric acid; continuous dialyzer; acid recovery;
D O I
10.1016/S0376-7388(01)00372-6
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A lumped-parameter model has been developed to predict the performances of diffusion dialysis using anion-exchange membrane (NEOSEPTA(R)-AFN) fur hydrochloric acid recovery in terms of various operating parameters. The operating parameters investigated in this study included the feed concentration, the retention time, and the ratio of reed to water (recipient) flow rate. The mass transfer coefficients of liquid films in continuous dialyzer were estimated from the Sherwood number (Sh) which was correlated to the Schmidt number (Sc) and the Reynolds number (Re). The results obtained from diffusion dialysis using continuous dialyzer showed that the model gave reasonably good agreement with the experimental results in predicting the recovery yield and the recovered acid concentration in the range of 0.05-3 mol dm(-3) HCl. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:61 / 70
页数:10
相关论文
共 13 条
[1]  
Bird R.B., 1960, TRANSPORT PHENOMENA, P640
[2]  
CUSSLER EL, 1984, DIFFUSION MASS TRANS, P150
[3]  
ECKERT ERG, 1972, ANAL HEAT MASS TRANS, P731
[4]   Diffusion coefficients of Br-2 in cation exchange membranes [J].
Heintz, A ;
Illenberger, C .
JOURNAL OF MEMBRANE SCIENCE, 1996, 113 (02) :175-181
[5]  
KAYS WM, 1964, COMPACT HEAT EXCHANG, P17
[6]   APPLICATION OF ION-EXCHANGE MEMBRANES TO THE RECOVERY OF ACIDS BY DIFFUSION DIALYSIS [J].
KOBUCHI, Y ;
MOTOMURA, H ;
NOMA, Y ;
HANADA, F .
JOURNAL OF MEMBRANE SCIENCE, 1986, 27 (02) :173-179
[7]  
KOBUCHI Y, 1986, P 1986 EUR JAP C MEM
[8]   DIFFUSION DIALYSIS TRANSPORT PHENOMENA BY IRREVERSIBLE THERMODYNAMICS [J].
NAREBSKA, A ;
WARSZAWSKI, A .
JOURNAL OF MEMBRANE SCIENCE, 1994, 88 (2-3) :167-175
[9]  
Oh SJ, 2000, J MEMBRANE SCI, V169, P95
[10]   Transport of sulfuric acid through anion-exchange membrane NEOSEPTA-AFN [J].
Palaty, Z ;
Zakova, A .
JOURNAL OF MEMBRANE SCIENCE, 1996, 119 (02) :183-190