Direct functionalisation of σ-aryl ligands:: preparation of homoleptic functionalised aryls of osmium(II)

被引：11

作者：

Lau, MK

Zhang, QF

Chim, JLC

Wong, WT

Leung, WH ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 16期

关键词：

D O I：

10.1039/b104075h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The osmium(rv) tetraaryl complex [Os(C8H9)(4)] (C8H9 = 2,5-dimethylphenyl) reacts with pyridinium tribromide in the presence of Fe powder to give [Os(C8H8Br)(4)], which undergoes Suzuki coupling with arylboronic acids to afford a series of homoleptic functionalised aryls of osmium(IV).

引用

页码：1478 / 1479

页数：2

共 15 条

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