Electrochemical synthesis of pyrrole through a polystyrene opal matrix

被引:20
作者
Misoska, V [1 ]
Price, W [1 ]
Ralph, S [1 ]
Wallace, G [1 ]
机构
[1] Univ Wollongong, IPRI, Dept Chem, Wollongong, NSW 2500, Australia
关键词
polypyrrole; electrochemical polymerisation; synthetic opals;
D O I
10.1016/S0379-6779(00)01526-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Conducting Polypyrrole/Cl- (Ppy/Cl) has been electrochemically prepared between the open void spaces in polystyrene synthetic opal crystal. The synthetic opal was formed by the sedimentation of colloidal polystyrene (ca. 315 nm) to produce self-assembled face centered cubic (fcc) films exhibiting opalescence. The voids between the colloids were filled by polypyrrole grown through opal deposited onto Indium-Tin-Oxide (ITO) glass slide or platinum coated PVFD filter. Electrochemical studies as well as UV-visible spectroscopic studies were conducted.
引用
收藏
页码:1501 / 1502
页数:2
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