Towards colombiasin A

被引:18
作者
Harrowven, DC [1 ]
Tyte, MJ [1 ]
机构
[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
关键词
cyclisation; lactones; natural products; terpenes and terpenoids;
D O I
10.1016/S0040-4039(01)01885-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A synthetic route to an unnatural diastereoisomer of colombiasin A is described. Key features are an arene alkylation with a gamma -methylene-gamma -butyrolactone and an intramolecular Diels-Alder cycloaddition. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8709 / 8711
页数:3
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