Toward functionalized conducting polymers:: synthesis and characterization of novel β-(Styryl)terthiophenes

被引：69

作者：

Collis, GE

Burrell, AK

机构：

[1] Los Alamos Natl Lab, CSIC, Los Alamos, NM 87545 USA

[2] Massey Univ, Nanomat Res Ctr, Palmerston North, New Zealand

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 23期

关键词：

D O I：

10.1021/jo034855g

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metal-catalyzed coupling methodologies have been employed in the synthesis of the key building block 3'-formyl-2,2':5',2"-terthiophene. Wittig olefinations with this aldehyde have produced five novel beta-styryl-substituted terthiophene monomers. These materials have been fully characterized by NMR spectroscopy, microanalysis, mass spectrometry, and X-ray crystal structure analysis. The results from the UV/visible spectroscopy and cyclic voltammetric investigations are reported.

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页码：8974 / 8983

页数：10

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