Zipper assembly of vectorial rigid-rod π-stack architectures with red and blue naphthalenediimides:: Toward supramolecular cascade n/p-heterojunctions

被引:97
作者
Sisson, Adam L. [2 ]
Sakai, Naomi [2 ]
Banerji, Natalie [1 ]
Fuerstenberg, Alexandre [1 ]
Vauthey, Eric [1 ]
Matile, Stefan [2 ]
机构
[1] Univ Geneva, Dept Phys Chem, Geneva, Switzerland
[2] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland
关键词
artificial photosynthesis; multicomponent reactions; photochemistry; solar energy; supramolecular chemistry;
D O I
10.1002/anie.200800203
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Zipped up: Supramolecular 3D organization on gold with interdigitating intra- and interlayer recognition motifs (see picure, black p-oligophenyl rods; red, blue naphthalenediimide (NDI) stacks) is designed to access supramolecular cascade n/p-heterojunctions or the adaptable directionality needed to control fill factors in current-voltage curves. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:3727 / 3729
页数:3
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