A tandem allylsilane-vinylsilane difunctionalization by silylcupration of allene followed by reaction with α,β-unsaturated nitriles

被引：22

作者：

Barbero, A ^{[1
]}

Blanco, Y ^{[1
]}

Pulido, FJ ^{[1
]}

机构：

[1] Univ Valladolid, Dept Quim Organ, E-47011 Valladolid, Spain

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b103387p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silylcupration of allene using phenyldimethylsilylcopper 1 followed by BF3-mediated reaction with alpha,beta -unsaturated nitriles at -40 degreesC affords allylsilane-vinylsilane-containing ketones resulting from consecutive addition (1,2 and 1,4) of the intermediate allyl- and vinylcopper species formed in the silylcupration of allene.

引用

页码：1606 / 1607

页数：2

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