A new convergent strategy for high-nuclearity metallodendrimers

被引：38

作者：

Constable, EC

Harverson, P

机构：

[1] Institut für Anorganische Chemie, CH-4056 Basel

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 01期

关键词：

D O I：

10.1039/cc9960000033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convergent methodology for the synthesis of metallodendrimers is described in which the key step is the reaction of a metal-complex containing a coordinated nucleophile with a multifunctional electrophile; using this methodology, linear and starburst tetra-, hexa- and nona-ruthenium metallodendrimers are prepared.

引用

页码：33 / 34

页数：2

共 14 条

[1] [Anonymous], PERSPECTIVE COORDINA
[2] [Anonymous], 1995, METALS LIGAND REACTI
[3] [Anonymous], 1991, PHOTOCHEMISTRY POLYP
[4] BALZANI V, 1990, TOP CURR CHEM, V158, P31
[5] Balzani V.S. F., 1991, Supramolecular Photochemistry
[6] HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2'/6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE)
CHOTALIA, R
CONSTABLE, EC
HANNON, MJ
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (22): : 3571 - 3580
[7] STRATEGIES FOR THE ASSEMBLY OF HOMO-NUCLEAR AND HETERO-NUCLEAR METALLOSUPRAMOLECULES CONTAINING 2,2'/6',2''-TERPYRIDINE METAL-BINDING DOMAINS
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (10): : 1615 - 1627
[8] SELF-ASSEMBLY OF A SUPRAMOLECULAR OLIGOMER CONTAINING 3 DIFFERENT COBALT(II) ENVIRONMENTS THE FIRST STRUCTURALLY CHARACTERIZED POLYMER-DERIVED FROM 2,3,5,6-TETRA(2-PYRIDYL)PYRAZINE (TPPZ)
CONSTABLE, EC
EDWARDS, AJ
PHILLIPS, D
RAITHBY, PR
[J]. SUPRAMOLECULAR CHEMISTRY, 1995, 5 (02) : 93 - 95
[9] METAL-MEDIATED SYNTHESIS OF MULTIDOMAIN LIGANDS - A NEW STRATEGY FOR METALLOSUPRAMOLECULAR CHEMISTRY
CONSTABLE, EC
THOMPSON, AMWC
HARVESON, P
MACKO, L
ZEHNDER, M
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (06) : 360 - 367
[10] CONSTABLE EC, 1994, TRANSITION METALS SU, P81

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