A new mixed metal titanate: The synthesis and characterization of Ba2Fe2Ti4O13

被引：13

作者：

Adams, RD ^{[1
]}

Layland, R ^{[1
]}

Danot, M ^{[1
]}

Payen, C ^{[1
]}

机构：

[1] INST MAT NANTES,F-44072 NANTES 03,FRANCE

来源：

POLYHEDRON | 1996年 / 15卷 / 15期

关键词：

D O I：

10.1016/0277-5387(95)00537-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new mixed metal titanate Ba2Fe2Ti4O13 (1) was obtained in crystalline form by heating a mixture of BaCO3, Fe3O4 and TiO2 at 1350 degrees C for 48 h. Compound 1 was characterized by single-crystal X-ray diffraction methods. It is isomorphous to the related known compounds Na2Ti6O13 and Ba2NiTi5O13. The X-ray diffraction and Mossbauer measurements of 1 obtained at room temperature indicate that the iron ions are unequally distributed between the three independent sites occupied by the transition metal ions. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2567 / 2571

页数：5

共 13 条

[1] A NEW MIXED-METAL TITANATE - THE SYNTHESIS AND CHARACTERIZATION OF BA2NITI5O13 [J].