An efficient binuclear catalyst for decomposition of formic acid

被引：105

作者：

Gao, Y ^{[1
]}

Kuncheria, J

Yap, GPA

Puddephatt, RJ

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Windsor, Dept Chem & Biochem, Windsor, ON N9B 3P4, Canada

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a805789c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [Ru-2(mu-CO)(CO)(4)(mu-dppm)(2)] is more active than mononuclear ruthenium complexes as a catalyst for decomposition of formic acid to CO2 and H-2; under conditions of highest activity, a coordinatively unsaturated diruthenium dihydride [Ru2H(mu-H)(mu-CO)(CO)(2)(mu-dppm)(2)] is present and can be isolated from solution.

引用

页码：2365 / 2366

页数：2

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