Polar substituent and solvent effects on the kinetics of radical reactions with thiols

被引：56

作者：

Tronche, C

Martinez, FN

Horner, JH

Newcomb, M

Senn, M

Giese, B

机构：

[1] WAYNE STATE UNIV,DEPT CHEM,DETROIT,MI 48202

[2] UNIV BASEL,DEPT CHEM,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 33期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(96)01241-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rates of thiol trapping of radicals depend upon polar substituents (Table 1) and solvent effects (Table 2). The rate accelerating effect of water on the reactions of biologically relevant radicals is of special importance. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：5845 / 5848

页数：4

共 16 条

[1] AKHLAQ MS, 1987, CARBOHYD RES, V164, P71
[2] DRAMATIC SOLVENT EFFECTS ON THE ABSOLUTE RATE CONSTANTS FOR ABSTRACTION OF THE HYDROXYLIC HYDROGEN-ATOM FROM TERT-BUTYL HYDROPEROXIDE AND PHENOL BY THE CUMYLOXYL RADICAL - THE ROLE OF HYDROGEN-BONDING
AVILA, DV
INGOLD, KU
LUSZTYK, J
GREEN, WH
PROCOPIO, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) : 2929 - 2930
[3] RATE CONSTANTS AND ARRHENIUS PARAMETERS FOR THE REACTIONS OF PRIMARY, SECONDARY, AND TERTIARY ALKYL RADICALS WITH TRI-NORMAL-BUTYLTIN HYDRIDE
CHATGILIALOGLU, C
INGOLD, KU
SCAIANO, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (26) : 7739 - 7742
[4] ORIGIN OF THE BETA-OXYGEN EFFECT IN THE BARTON DEOXYGENATION REACTION
CRICH, D
BECKWITH, ALJ
CHEN, C
YAO, QW
DAVISON, IGE
LONGMORE, RW
DEPARRODI, CA
QUINTEROCORTES, L
SANDOVALRAMIREZ, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (34) : 8757 - 8768
[5] ABSOLUTE RATE EXPRESSIONS FOR THE ABSTRACTION OF HYDROGEN BY PRIMARY, SECONDARY, AND TERTIARY ALKYL RADICALS FROM THIOPHENOL
FRANZ, JA
BUSHAW, BA
ALNAJJAR, MS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 268 - 275
[6] THE CHEMISTRY OF SINGLE-STRANDED 4'-DNA RADICALS - INFLUENCE OF THE RADICAL PRECURSOR ON ANAEROBIC AND AEROBIC STRAND CLEAVAGE
GIESE, B
BEYRICHGRAF, X
ERDMANN, P
PETRETTA, M
SCHWITTER, U
[J]. CHEMISTRY & BIOLOGY, 1995, 2 (06): : 367 - 375
[7] ABSOLUTE KINETICS OF ALPHA-METHOXY RADICAL REACTIONS - A FOUNDATION FOR A KINETIC SCALE FOR ALPHA-ALKOXY RADICAL REACTIONS
JOHNSON, CC
HORNER, JH
TRONCHE, C
NEWCOMB, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (06) : 1684 - 1687
[8] ELECTRON-SPIN-RESONANCE SPECTROSCOPIC INVESTIGATION OF CARBOHYDRATE RADICALS .6. CONFORMATIONAL EFFECTS IN 2-DEOXYGLUCOPYRANOS-1-YL RADICALS
KORTH, HG
SUSTMANN, R
GIESE, B
RUCKERT, B
GRONINGER, KS
[J]. CHEMISCHE BERICHTE, 1990, 123 (09) : 1891 - 1898
[9] KINETICS FOR THE REACTION OF A SECONDARY ALKYL RADICAL WITH TRI-N-BUTYLGERMANIUM HYDRIDE AND CALIBRATION OF A SECONDARY ALKYL RADICAL CLOCK REACTION
LUSZTYK, J
MAILLARD, B
DEYCARD, S
LINDSAY, DA
INGOLD, KU
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (16) : 3509 - 3514
[10] SOLVENT EFFECTS ON SPIN-TRAPPING OF PRIMARY ALKYL RADICALS
MAEDA, Y
SCHMID, P
GRILLER, D
INGOLD, KU
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (13) : 525 - 526

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