New separation of variables method for composite electrodes with galvanostatic boundary conditions

被引：56

作者：

Subramanian, VR ^{[1
]}

White, RE ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem Engn, Ctr Electrochem Engn, Columbia, SC 29208 USA

来源：

JOURNAL OF POWER SOURCES | 2001年 / 96卷 / 02期

关键词：

composite electrode; galvanostatic boundary conditions; Laplace transform;

D O I：

10.1016/S0378-7753(00)00656-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The separation of variables method is extended to obtain concentration profiles in a particle electrode under galvanostatic boundary conditions. The method is also used to find exact analytical solutions for composite slab and spherical electrodes. Finally, the method is used to obtain a solution for a lithium/polymer cell model that was presented previously by Doyle and Newman. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：385 / 395

页数：11