Fluoro-Substituted n-Type Conjugated Polymers for Additive-Free All-Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71%

被引:416
作者
Jung, Jae Woong [1 ]
Jo, Jea Woong [2 ]
Chueh, Chu-Chen [1 ]
Liu, Feng [3 ]
Jo, Won Ho [2 ]
Russell, Thomas P. [3 ]
Jen, Alex K. -Y. [1 ,4 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151744, South Korea
[3] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
[4] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
all-polymer solar cells; conjugated polymers; fluorination; naphthalene di-imide; FIELD-EFFECT TRANSISTORS; OPEN-CIRCUIT VOLTAGE; PERFORMANCE; MOBILITY; DIKETOPYRROLOPYRROLE; FULLERENE; AGGREGATION; SOLUBILITY; ACCEPTORS; DIIMIDE;
D O I
10.1002/adma.201501214
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorinated n-type conjugated polymers are used as efficient electron acceptor to demonstrate high-performance all-polymer solar cells. The exciton generation, dissociation, and charge-transporting properties of blend films are improved by using these fluorinated n-type polymers to result in enhanced photocurrent and suppressed charge recombination. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3310 / 3317
页数:8
相关论文
共 53 条
[1]   Fluorinated organic materials for electronic and optoelectronic applications: the role of the fluorine atom [J].
Babudri, Francesco ;
Farinola, Gianluca M. ;
Naso, Francesco ;
Ragni, Roberta .
CHEMICAL COMMUNICATIONS, 2007, (10) :1003-1022
[2]   Fluorinated poly(p-phenylenevinylene) copolymers: Preparation and use in light-emitting diodes [J].
Benjamin, I ;
Faraggi, EZ ;
Avny, Y ;
Davidov, D ;
Neumann, R .
CHEMISTRY OF MATERIALS, 1996, 8 (02) :352-355
[3]   Chemistry of naphthalene diimides [J].
Bhosale, Sheshanath V. ;
Jani, Chintan H. ;
Langford, Steven J. .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (02) :331-342
[4]   Linear Side Chains in Benzo[1,2-b:4,5-b′]dithiophene-Thieno[3,4-c]pyrrole-4,6-dione Polymers Direct Self-Assembly and Solar Cell Performance [J].
Cabanetos, Clement ;
El Labban, Abdulrahman ;
Bartelt, Jonathan A. ;
Douglas, Jessica D. ;
Mateker, William R. ;
Frechet, Jean M. J. ;
McGehee, Michael D. ;
Beaujuge, Pierre M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (12) :4656-4659
[5]   Polymer solar cells with enhanced open-circuit voltage and efficiency [J].
Chen, Hsiang-Yu ;
Hou, Jianhui ;
Zhang, Shaoqing ;
Liang, Yongye ;
Yang, Guanwen ;
Yang, Yang ;
Yu, Luping ;
Wu, Yue ;
Li, Gang .
NATURE PHOTONICS, 2009, 3 (11) :649-653
[6]   Systematic Investigation of Side-Chain Branching Position Effect on Electron Carrier Mobility in Conjugated Polymers [J].
Dou, Jin-Hu ;
Zheng, Yu-Qing ;
Lei, Ting ;
Zhang, Shi-Ding ;
Wang, Zhi ;
Zhang, Wen-Bin ;
Wang, Jie-Yu ;
Pei, Jian .
ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (40) :6270-6278
[7]   All-Polymer Solar Cells with 3.3% Efficiency Based on Naphthalene Diimide-Selenophene Copolymer Acceptor [J].
Earmme, Taeshik ;
Hwang, Ye-Jin ;
Murari, Nishit M. ;
Subramaniyan, Selvam ;
Jenekhe, Samson A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (40) :14960-14963
[8]   Recent advances of non-fullerene, small molecular acceptors for solution processed bulk heterojunction solar cells [J].
Eftaiha, Ala'a F. ;
Sun, Jon-Paul ;
Hill, Ian G. ;
Welch, Gregory C. .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (05) :1201-1213
[9]   Polymer donor-polymer acceptor (all-polymer) solar cells [J].
Facchetti, Antonio .
MATERIALS TODAY, 2013, 16 (04) :123-132
[10]   Fluorinated Poly(p-phenylenevinylene)s: Synthesis and Optical Properties of an Intriguing Class of Luminescent Polymers [J].
Farinola, Gianluca M. ;
Cardone, Antonio ;
Babudri, Francesco ;
Martinelli, Carmela ;
Naso, Francesco ;
Bruno, Giovanni ;
Losurdo, Maria .
MATERIALS, 2010, 3 (05) :3077-3091