Silver and thallium ion complexation with allyloxycalix[4]arenes

被引：18

作者：

Couton, D

Mocerino, M

Rapley, C

Kitamura, C

Yoneda, A

Ouchi, M

机构：

[1] Curtin Univ Technol, Sch Appl Chem, Perth, WA 6845, Australia

[2] Himeji Inst Technol, Fac Engn, Dept Appl Chem, Himeji, Hyogo 6712201, Japan

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 03期

关键词：

D O I：

10.1071/C98175

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of six calix[4]arene derivatives bearing allyl groups and/or benzyl groups functionalized at the phenolic oxygen atoms were synthesized and their cation-binding abilities for silver(I) and thallium(I) ions were evaluated through solvent extraction experiments. The results showed that both silver(I) and thallium(I) picrates were readily extracted by the tetrasubstituted p-t-butylcalixarene derivatives, while no extraction of sodium or potassium picrates was observed. The high extractability of thallium(I) picrate by these ligands was independent of the functional groups present, but the extraction of silver picrate seemed to be dependent on the conformational rigidity of the calixarene; those locked into the cone conformation showed the highest extractability for silver picrate.

引用

收藏

页码：227 / 229

页数：3

相关论文

共 15 条

[1] AN EASY ACCESS TO TETRA-O-ALKYLATED CALIX[4]ARENES OF CONE CONFORMATION [J].

BITTER, I ;

GRUN, A ;

AGAI, B ;

TOKE, L .

TETRAHEDRON, 1995, 51 (28) :7835-7840

[2] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES [J].

BOHMER, V .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :713-745

[3] 'Soft' calixarenes - Structural aspects of calixarene allyl ethers and of thiacalixarene synthesis [J].

Delaigue, X ;

Harrowfield, JM ;

Hosseini, MW ;

Mocerino, M ;

Skelton, BW ;

White, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1998, 51 (02) :111-121

[4] EXODITOPIC RECEPTORS .1. SYNTHESIS AND STRUCTURAL STUDIES ON P-TERT-BUTYLTETRAMERCAPTOCALIX[4]ARENE AND ITS MERCURY COMPLEXES [J].

DELAIGUE, X ;

HARROWFIELD, JM ;

HOSSEINI, MW ;

DECIAN, A ;

FISCHER, J ;

KYRITSAKAS, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (13) :1579-1580

[5] KINETICALLY STABLE COMPLEXES OF ALKALI CATIONS WITH RIGIDIFIED CALIX[4]ARENES - SYNTHESIS, X-RAY STRUCTURES, AND COMPLEXATION OF CALIXCROWNS AND CALIXSPHERANDS [J].

DIJKSTRA, PJ ;

BRUNINK, JAJ ;

BUGGE, KE ;

REINHOUDT, DN ;

HARKEMA, S ;

UNGARO, R ;

UGOZZOLI, F ;

GHIDINI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7567-7575

[6] CALIXARENES-9 - CONFORMATIONAL ISOMERS OF THE ETHERS AND ESTERS OF CALIX[4]ARENES [J].

GUTSCHE, CD ;

DHAWAN, B ;

LEVINE, JA ;

NO, KH ;

BAUER, LJ .

TETRAHEDRON, 1983, 39 (03) :409-426

[7] METAL-ION BINDING TO CALIXARENES - PENDENT ARM COORDINATION ASSISTED BY SELF-INCLUSION [J].

HARROWFIELD, JM ;

MOCERINO, M ;

SKELTON, BW ;

WHITAKER, CR ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1994, 47 (06) :1185-1192

[8] CALIXARENE-CUPPED CESIUM - A COORDINATION CONUNDRUM [J].

HARROWFIELD, JM ;

OGDEN, MI ;

RICHMOND, WR ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) :1159-1161

[9]

IKEDA A, 1994, J CHEM SOC P2, P2037

[10] Calix[4]arene derivative bearing π-coordinate substituents as neutral carrier for silver ion sensors [J].

Kimura, K ;

Tatsumi, K ;

Yajima, S ;

Miyake, S ;

Sakamoto, H ;

Yokoyama, M .

CHEMISTRY LETTERS, 1998, (08) :833-834