Cobaloxime-based photocatalytic devices for hydrogen production

被引：389

作者：

Fihri, Aziz ^{[1
]}

Artero, Vincent ^{[1
]}

Razavet, Mathieu ^{[1
]}

Baffert, Carole ^{[1
]}

Leibl, Winfried ^{[2
]}

Fontecave, Marc ^{[1
]}

机构：

[1] Univ Grenoble 1, CEA Grenoble, Lab Chim & Biol Metaux, CNRS,UMR 5249,DSV iRTSV, F-38054 Grenoble 9, France

[2] CEA, Lab Photocatalyse & Biohydrogene, DSV iBiTecS, CNRS,URA 2096, Gif Sur Yvette, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

cobaloxime; hydrogen; photolysis; ruthenium; supramolecular chemistry;

D O I：

10.1002/anie.200702953

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) It is the dawning of the age of supramolecular photocatalysts for H2 production using first-row transition-metal catalytic centers. These catalysts consist of a ruthenium tris(diimine) light-harvesting unit covalently linked to various catalytic cobaloxime centers (see picture). The catalyst stability, CoII/CoI redox potential, and nucleophilicity of the cobaloxime moiety all affect the photocatalytic properties. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：564 / 567

页数：4

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