Transfer hydrogenation of carbonyl compounds catalyzed by a ruthenium-acetamido complex: Evidence for a stepwise hydrogen transfer mechanism

被引：55

作者：

Yi, CS ^{[1
]}

He, ZJ

Guzei, IA

机构：

[1] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 17期

关键词：

D O I：

10.1021/om010560m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium-acetamido complex, prepared from the reaction of [(PCy3)(2)(CO)(CH3CN)(2)RuH](+)-BF4- with KOH in 2-propanol, was found to be an effective catalyst for the transfer hydrogenation of carbonyl compounds and imines. Observation of both the inverse deuterium isotope effect and the competitive inhibition by added phosphine provided strong evidence for a stepwise mechanism of proton and hydride transfer via a coordinatively unsaturated ruthenium-amido species.

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页码：3641 / 3643

页数：3

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