Main-chain-type N,N′-chelate organoboron ammoquinolate polymers:: Synthesis, luminescence, and energy transfer behavior

被引：56

作者：

Nagata, Yuuya ^{[1
]}

Chujo, Yoshiki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

MACROMOLECULES | 2008年 / 41卷 / 10期

关键词：

D O I：

10.1021/ma702873a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel green luminescent compound, (k(2)-(N,N')-8-acetylaminoquinolate)diphenylborane (1) was synthesized and fully characterized. To incorporate into the polymer main-chain, (k(2)-(N,N')-8-acetylaminoquinolate)bis(4-iodophenyl)borane was also synthesized as a monomer. A new class of fluorescent main-chain type organoboron aminoquinolate polymers were prepared by means of the Sonogashira-Hagihara coupling reaction between diyne monomers and the aminoquinoline monomer. The obtained polymers were further investigated by UV-vis absorption and fluorescence spectroscopy. It was revealed that the fluorescent quantum efficiencies of the obtained polymers depended on the pi-conjugated linker unit. In addition, an efficient energy transfer was observed and well pi-extended linker units played a role in a light harvesting antenna for the organoboron aminoquinolate units.

引用

页码：3488 / 3492

页数：5

共 40 条

[1]

AbdElAziz AS, 2007, MACROMOL CONTAIN MET, V8, P1

[2] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[3] Materials for organic electroluminescence: aluminium vs. boron [J].

Anderson, S ;

Weaver, MS ;

Hudson, AJ .

SYNTHETIC METALS, 2000, 111 :459-463

[4] Diboron and triboron compounds based on linear and star-shaped conjugated Ligands with 8-hydroxyquinolate functionality: Impact of intermolecular interaction and boron coordination on luminescence [J].

Cui, Yi ;

Wang, Suning .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (17) :6485-6496

[5]

Dennington R., 2008, GAUSSVIEW VERSION 5

[6]

Farrugia L.J., 1997, J APPL CRYSTALLOGR, V30, P565

[7]

FROSCJ MJ, 2004, GAUSSIAN 03 REVISION

[8] ACTINOMETRIC DETERMINATION OF ABSOLUTE FLUORESCENCE QUANTUM YIELDS [J].

HAMAI, S ;

HIRAYAMA, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (01) :83-89

[9]

Heuer H. W., 2000, Patent No. [DE 19829949 A1, 19829949]

[10]

HIGASHI T, 1995, BASCOR PROGRAM ABSOR

← 1 2 3 4 →