New reaction mode of the Horner-Wadsworth-Emmons reaction using Sn(OSO2CF3)(2) and N-ethylpiperidine

被引：42

作者：

Sano, S ^{[1
]}

Yokoyama, K ^{[1
]}

Fukushima, M ^{[1
]}

Yagi, T ^{[1
]}

Nagao, Y ^{[1
]}

机构：

[1] UNIV TOKUSHIMA,FAC PHARMACEUT SCI,TOKUSHIMA 770,JAPAN

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a608495h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Excellent Z or E selectivity is observed in the Horner-Wadsworth-Emmons reactions of methyl bis(trifluoroethyl)phosphonoacetate 2 with aryl alkyl ketones 3a-d or aldehydes 3f,g using Sn(OSO2CF3)(2) in the presence of N-ethylpiperidine, which should have a different reaction mode to those using sodium hydride.

引用

页码：559 / 560

页数：2

共 11 条

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