Template-controlled synthesis in the solid-state

被引：102

作者：

MacGillivray, LR ^{[1
]}

Papaefstathiou, GS ^{[1
]}

Friscic, T ^{[1
]}

Varshney, DB ^{[1
]}

Hamilton, TD ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52245 USA

来源：

TEMPLATES IN CHEMISTRY I | 2004年 / 248卷

关键词：

linear templates; photodimerization; hydrogen-bonding; preorganization; molecular recognition; self-assembly;

D O I：

10.1007/b99914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The application of molecular templates to direct reactivity in the solid state is described. Specifically, molecules that function as linear templates are demonstrated to provide control of the [2+2] photodimerization in the solid state such that it is possible to use the templates to conduct target-oriented molecular syntheses, or molecular syntheses by design. The degree of organization provided by the solid state is also shown to provide chemists a reliable means to capture and transform ordered complexes formed by way of hydrogen-bonded-driven self-assembly into complex covalent molecular and polymeric structures.

引用

页码：201 / 221

页数：21

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