Synthesis and crystal structure of a novel vanadium-containing tungstobismutate(III) K12[(VO)3(BiW9O33)2] • 30H2O

被引：34

作者：

Botar, B ^{[1
]}

Yamase, T ^{[1
]}

Ishikawa, E ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 10期

基金：

日本学术振兴会;

关键词：

crystal structure; tris(vanadyl)-substituted tungstobismutate(III); alpha-B tungstobismutate; V/W/Bi-mixed polyanion;

D O I：

10.1016/S1387-7003(01)00263-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tris(vanadyl)-substituted tungstobismutate (III) [(VO)(3)(BiW9O33)(2)](12-) anion has been synthesized by reaction of alpha -B[BiW9O33](9-) with VOSO4 in aqueous solution. The anion is made of two alpha -B[BiW9O33](9-) units linked by a belt of three exterior VO2+ groups into an assembly of virtual D-3h symmetry. The three vanadium centers are well separated by a V . . .V distance of 5.375(4)-5.474(4) Angstrom. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：551 / 554

页数：4

共 15 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods
ALTOMARE, A
CASCARANO, G
GIACOVAZZO, G
GUAGLIARDI, A
BURLA, MC
POLIDORI, G
CAMALLI, M
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 435 - 435
[2] New strategies for the generation of large heteropolymetalate clusters: The beta-B-SbW9 fragment as a multifunctional unit
Bosing, M
Loose, I
Pohlmann, H
Krebs, B
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) : 1232 - 1237
[3] Highly efficient catalysts in directed oxygen-transfer processes:: Synthesis, structures of novel manganese-containing heteropolyanions, and applications in regioselective epoxidation of dienes with hydrogen peroxide
Bösing, M
Nöh, A
Loose, I
Krebs, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) : 7252 - 7259
[4] A highly nuclear vanadium-containing tungstobismutate:: synthesis and crystal structure of K11H[(BiW9O33)3Bi6(OH)3(H2O)3V4O10]•25 H2O
Botar, B
Yamase, T
Ishikawa, E
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2000, 3 (11) : 579 - 584
[5] BOTAR B, UNPUB
[6] FISCHER J, 1976, J AM CHEM SOC, V98, P3050, DOI 10.1021/ja00426a081
[7] HIGASHI T, 1999, SHAPE PROGRAM OBTAIN
[8] HIGASHI T, 1999, NUMBAS NUMERICAL ABS
[9] *MOL STRUCT CORP, 1989, TEXSAN SINGL CRYST S
[10] CRYSTAL-STRUCTURE OF AMMONIUM DICOBALTO(II)-40-TUNGSTOTETRAARSENATE(III) - ALLOSTERIC EFFECTS IN THE LIGAND
ROBERT, F
LEYRIE, M
HERVE, G
TEZE, A
JEANNIN, Y
[J]. INORGANIC CHEMISTRY, 1980, 19 (06) : 1746 - 1752

← 1 2 →