Conformational diastereoisomers of PPh3 coordinated to stereogenic metal centres as molecular optical switches

被引：15

作者：

Ayscough, AP

Costello, JF

Davies, SG

机构：

[1] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

[2] Univ W England, Dept Chem, Bristol BS16 1QY, Avon, England

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(01)00253-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The specific rotation of (R-Fe,R,M)-4 switches sign upon epimerisation to (R-Fe,S,P)-5. X-Ray crystallographic studies suggest that inversion of the propeller configuration of the coordinated PPh3 ligand is a major contributor to the switch of specific rotation. A simple model for predicting the conformational diastereoisomeric forms of PPh3 is presented, suggesting future routes towards the design of molecular optical switching devices. (C) 2001 Elsevier Science Ltd. All rights reserved.

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页码：1621 / 1624

页数：4

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