Changes in the structure of AgI-AgPO3 around the glass transition temperature

被引：10

作者：

Matic, A ^{[1
]}

Borjesson, L ^{[1
]}

Wannberg, A ^{[1
]}

McGreevy, RL ^{[1
]}

机构：

[1] STUDSVIK NEUTRON RES LAB,S-61182 NYKOPING,SWEDEN

来源：

SOLID STATE IONICS | 1996年 / 86-8卷 / pt 1期

关键词：

structure factor; glass transition temperature; superionic glass;

D O I：

10.1016/0167-2738(96)00165-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Neutron diffraction experiments were performed on the superionic glass AgI-AgPO3 in the temperature range 293-403 K. We report preliminary results on significant changes in S(Q) in the range 2-6 Angstrom(-1) as the temperature exceeds T-g. Corresponding changes are observed in G(r) in the range 3-5 Angstrom. The changes are believed to be connected to temperature-induced rearrangements of Ag ions in the structure. The first sharp diffraction peak at the low Q-value of 0.7 Angstrom(-1), which indicates significant intermediate range ordering is, however, unaffected by temperature.

引用

页码：421 / 424

页数：4

共 10 条

[1] MOBILE IONS IN AMORPHOUS SOLIDS [J].