Catalytic combustion of methane on aluminate-supported copper oxide

被引:49
作者
Artizzu, P
Garbowski, E
Primet, M
Brulle, Y
Saint-Just, J
机构
[1] Univ Lyon 1, LACE, F-69622 Villeurbanne, France
[2] Gaz France, DR, CERSTA, DCPC, F-93211 La Plaine St Denis, France
关键词
copper oxide; spinel support; methane and natural gas combustion; gas turbine;
D O I
10.1016/S0920-5861(98)00285-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Copper oxide has been deposited onto high surface area magnesium aluminate spinel prepared from alumina and magnesium nitrate. The catalytic properties of such a solid have been investigated in methane combustion. At the laboratory scale a very good activity is observed (light-off of 530 degrees C) and no CO is detected. Aging at 1000 degrees C under water vapour has no influence on activity. The previous catalyst has been washcoated on monolith and tested on a rig either with methane or synthetic natural gas at very high GHSV under conditions close to those of a gas turbine. In that case also, a good activity was observed. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:83 / 93
页数:11
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