Ultrafast dynamics and energetics of the intracluster harpooning reaction in Ba•••FCH3

被引：24

作者：

Farmanara, P

Stert, V

Radloff, W

Skowronek, S

Gonzalez-Ureña, A

机构：

[1] Max Born Inst Nichtlineare Opt & Spektroskopie, D-12489 Berlin, Germany

[2] Univ Complutense Madrid, Inst Pluridisciplinar, Unidad Laseres & Haces Mol, E-28040 Madrid, Spain

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 304卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(99)00318-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Applying the pump-probe technique with femtosecond laser pulses we have determined an intracluster reaction time of (270 +/- 30) fs in Ba ... FCH3 after resonant excitation of the complex at 618 nm. The BaF reaction product is formed within this time in an electronically excited state whose energy has been estimated from the energy balance of the reaction. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：127 / 133

页数：7

共 10 条

[1] The Rydberg spectrum of CaF and BaF: Calculation by R-matrix and generalized quantum defect theory [J].