Synthesis of crystallized TaON and Ta3N5 by nitridation of Ta2O5 thin films grown by pulsed laser deposition

被引:43
作者
Kerlau, M
Merdrignac-Conanec, O [1 ]
Guilloux-Viry, M
Perrin, A
机构
[1] Univ Rennes 1, Inst Chim Rennes, Lab Verres & Ceram, CNRS,UMR 6512, F-35042 Rennes, France
[2] Univ Rennes 1, Inst Chim Rennes, Chim Solide & Inorgan Mol Lab, CNRS,UMR 6511, F-35042 Rennes, France
关键词
TaON; Ta3N5; Ta2O5; synthesis; nitridation; thin film; pulsed laser deposition;
D O I
10.1016/j.solidstatesciences.2003.10.010
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
TaON and Ta3N5 thin films of different thicknesses were prepared by pulsed laser deposition of tantalum oxide followed by ex situ thermal nitridation under ammonia. The nitridation was carried out in flowing gas in the 600-800 degreesC temperature range. The dependence of tantalum oxynitride and nitride crystalline phases formation on nitridation reaction parameters was investigated. Structural and microstructural characteristics were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). (C) 2003 Elsevier SAS. All rights reserved.
引用
收藏
页码:101 / 107
页数:7
相关论文
共 36 条
[1]   Nitrogen plasma annealing for low temperature Ta2O5 films [J].
Alers, GB ;
Fleming, RM ;
Wong, YH ;
Dennis, B ;
Pinczuk, A ;
Redinbo, G ;
Urdahl, R ;
Ong, E ;
Hasan, Z .
APPLIED PHYSICS LETTERS, 1998, 72 (11) :1308-1310
[2]   CHARACTERIZATION OF TANTALUM OXYNITRIDE THIN-FILMS AS HIGH-TEMPERATURE STRAIN-GAUGES [J].
AYERDI, I ;
CASTANO, E ;
GARCIAALONSO, A ;
GRACIA, FJ .
SENSORS AND ACTUATORS A-PHYSICAL, 1995, 46 (1-3) :218-221
[3]   Synthesis and properties of tantalum nitride films formed by ion beam assisted deposition [J].
Baba, K ;
Hatada, R .
SURFACE & COATINGS TECHNOLOGY, 1996, 84 (1-3) :429-433
[4]   Synthesis of tantalum pentoxide films by pulsed laser deposition: material characterization and scale-up [J].
Boughaba, S ;
Sproule, GI ;
McCaffrey, JP ;
Islam, M ;
Graham, MJ .
THIN SOLID FILMS, 2000, 358 (1-2) :104-113
[5]   Ultrathin Ta2O5 films produced by large-area pulsed laser deposition [J].
Boughaba, S ;
Islam, M ;
McCaffrey, JP ;
Sproule, GI ;
Graham, MJ .
THIN SOLID FILMS, 2000, 371 (1-2) :119-125
[6]   SYNTHESIS AND PROPERTIES OF TANTALUM OXIDE NITRIDE TAON [J].
BRAUER, G ;
WEIDLEIN, JR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (10) :875-&
[7]   UBER DAS TANTALNITRID TA3N5 UND DAS TANTALOXIDNITRID TAON [J].
BRAUER, G ;
WEIDLEIN, J ;
STRAHLE, J .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1966, 348 (5-6) :298-&
[8]   STRUCTURE OF TA3N5 AT 16-K BY TIME-OF-FLIGHT NEUTRON-DIFFRACTION [J].
BRESE, NE ;
OKEEFFE, M ;
RAUCH, P ;
DISALVO, FJ .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :2291-2294
[9]   Phase formation behavior and diffusion barrier property of reactively sputtered tantalum-based thin films used in semiconductor metallization [J].
Chen, GS ;
Lee, PY ;
Chen, ST .
THIN SOLID FILMS, 1999, 353 (1-2) :264-273
[10]   Growth mechanism of sputter deposited Ta and Ta-N thin films induced by an underlying titanium layer and varying nitrogen flow rates [J].
Chen, GS ;
Chen, ST ;
Huang, SC ;
Lee, HY .
APPLIED SURFACE SCIENCE, 2001, 169 :353-357