Structure of (PhCCH)3Co2(CO)6:: A new Co2(CO)8 catalyzed oligomerization sequence of an alkyne and carbon monoxide

被引：9

作者：

Baxter, RJ ^{[1
]}

Knox, GR ^{[1
]}

Pauson, PL ^{[1
]}

Spicer, MD ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 02期

关键词：

D O I：

10.1021/om980546i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hubel's tris(ethynylbenzene)hexacarbonyldicobalt complex, (PhC=CH)(3)Co-2(CO)(6), a byproduct in cobaltacyclopentadiene formation, has been characterized by spectroscopic methods and a single-crystal X-ray diffraction analysis. The organic ligand, derived from the ester [(1,2,3,4,5-eta)-2,5-diphenylcyclopenta-2,4-dienyl][(2-eta)(3-eta:3-eta)]-2H-3-phenylpropynoate, forms a eta(1):eta(2)-bridge between the two cobalt atoms linked by a "semibridging" carbonyl.

引用

页码：215 / 218

页数：4

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