P(CH3NCH2CH2)(3)N: A nonionic superbase for efficient dehydrohalogenation

被引：53

作者：

Arumugam, S ^{[1
]}

Verkade, JG ^{[1
]}

机构：

[1] IOWA STATE UNIV,DEPT CHEM,AMES,IA 50011

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1997年 / 62卷 / 14期

关键词：

D O I：

10.1021/jo962310z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The commercially available nonionic superbase P(CH3NCH2CH2)(3)N (1) is far superior to DBU for the conversion of primary and secondary alkyl halides to alkenes. A reason for the efficacy of acetonitrile as a solvent for the halides requiring extended reaction times is presented.

引用

页码：4827 / 4828

页数：2

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