Photocurrent generation of poly(titanyloxo-phthalocyanine)s and silica hybrid film

被引：8

作者：

Han, DS

Lee, YJ

Kim, JS

Kim, E ^{[1
]}

机构：

[1] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

[2] Chungnam Natl Univ, Dept Polymer Sci & Engn, Taejon 305764, South Korea

来源：

SYNTHETIC METALS | 2001年 / 117卷 / 1-3期

关键词：

photoconductivity; sol-gel process; poly(titanyloxo-phthalocyanine)s; silica hybrid film; photocurrent;

D O I：

10.1016/S0379-6779(00)00501-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Photoelectric properties of poly(titanyloxo-phthalocyanine) bound silica hybrid film were investigated. The solution for the silic a hybrid film consists of soluble poly(titanyloxo-pfithalocyanine) (PTiOPc) and a sol solution prepared from the hydrolysis of r-glycidoxypropyl-trimethoxysilane and methyl trimethoxysilane. PTiOPc-silica hybrid films were prepared from the above solution by sol-gel process, to give transparent film. The film showed pencil hardness of 3-H when coated on a glass substrate. The PTiOPc-silica hybrid films coated on an ITO glass showed photocurrent higher than 4 muA/cm(2), upon excitation with a visible light under an external potential of 0.6 V (versus Ag/AgCl). The photoconductivity was not much affected by the bridging group between the phthalocyanine ring, but linearly dependent on the content of PTiOPc up to 40 wt. %.. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：203 / 205

页数：3

共 7 条

[1] Dispersion of the nonlinear absorption of copper phthalocyanine in a silica xerogel matrix through the visible spectrum [J].