Bifunctional hydrogen bonding of 2-chloroethyl ethyl sulfide on TiO2-SiO2 powders

被引：47

作者：

Panayotov, D ^{[1
]}

Yates, JT ^{[1
]}

机构：

[1] Univ Pittsburgh, Ctr Surface Sci, Dept Chem, Pittsburgh, PA 15260 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2003年 / 107卷 / 38期

关键词：

D O I：

10.1021/jp0304273

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of 2-chloroethyl ethyl sulfide on a high area TiO2-SiO2 mixed oxide powder has been studied by transmission infrared spectroscopy. It has been found that hydrogen bonding of this molecule to Si-OH groups occurs through both the Cl and the S moieties and that characteristic Si-OH red-shifts are found for each of the hydrogen bonds produced. A similar pattern of hydrogen bonding is found for the interaction of 2-chloroethyl ethyl sulfide with OH groups on TiO2 surfaces.

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页码：10560 / 10564

页数：5

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