Vibrational relaxation of a polyatomic solute in a polyatomic supercritical fluid near the critical point

被引：38

作者：

Urdahl, RS

Rector, KD

Myers, DJ

Davis, PH

Fayer, MD

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 105卷 / 19期

关键词：

D O I：

10.1063/1.472628

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibrational lifetimes and absorption spectra of the asymmetric CO stretching mode (similar to 1990 cm(-1)) of W(CO)(6) in supercritical CO2 are reported as functions of solvent density and temperature. Close to the critical temperature, the observables are density independent over a twofold range of density. Possible explanations are discussed for this unique behavior. (C) 1996 American Institute of Physics.

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页码：8973 / 8976

页数：4

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