Raman spectra of hydrogen and deuterium adsorbed on a metal-organic framework

被引：55

作者：

Centrone, A

Siberio-Pérez, DY

Millward, AR

Yaghi, OM

Matzger, AJ

Zerbi, G

机构：

[1] Politecn Milan, Dipartimento Chim, I-20133 Milan, Italy

[2] Politecn Milan, Ctr Eccellenza Ingn Mat & Superfici Nanostruttura, NEMAS, I-20133 Milan, Italy

[3] Univ Michigan, Macromol Sci & Engn Program, Ann Arbor, MI 48109 USA

[4] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 411卷 / 4-6期

基金：

美国能源部;

关键词：

D O I：

10.1016/j.cplett.2005.06.069

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Raman spectra of H-2 and D-2 adsorbed on metal-organic framework-5 at various pressures (H-2: 12.8 and 30.3 bar; D-2: 2.2-24.5 bar) and temperatures (H,: 298 K; D,: 40-300 K) have been recorded. The shifts observed in the vibrational modes of the gases indicate that physisorption is responsible for the attractive interactions between the gas and the framework; these interactions are larger with respect to those detected for carbon materials. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：516 / 519

页数：4

共 23 条

[1] RAMAN SPECTRA OF LIQUID AND SOLID H2, D2, AND HD AT HIGH RESOLUTION
BHATNAGAR, SS
WELSH, HL
ALLIN, EJ
[J]. CANADIAN JOURNAL OF PHYSICS, 1962, 40 (01) : 9 - &
[2] Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour
Bordiga, S
Lamberti, C
Ricchiardi, G
Regli, L
Bonino, F
Damin, A
Lillerud, KP
Bjorgen, M
Zecchina, A
[J]. CHEMICAL COMMUNICATIONS, 2004, (20) : 2300 - 2301
[3] Adsorption of H2 on carbon-based materials:: A Raman spectroscopy study -: art. no. 245406
Centrone, A
Brambilla, L
Zerbi, G
[J]. PHYSICAL REVIEW B, 2005, 71 (24)
[4] CENTRONE A, IN PRESS
[5] A route to high surface area, porosity and inclusion of large molecules in crystals
Chae, HK
Siberio-Pérez, DY
Kim, J
Go, Y
Eddaoudi, M
Matzger, AJ
O'Keeffe, M
Yaghi, OM
[J]. NATURE, 2004, 427 (6974) : 523 - 527
[6] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage
Eddaoudi, M
Kim, J
Rosi, N
Vodak, D
Wachter, J
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2002, 295 (5554) : 469 - 472
[7] *FREED INT US DEP, 2003, SEE SOL NUMB DE PS36
[8] Herzberg G., 1950, MOL SPECTRA MOL STRU
[9] Are carbon nanostructures an efficient hydrogen storage medium?
Hirscher, M
Becher, M
Haluska, M
von Zeppelin, F
Chen, XH
Dettlaff-Weglikowska, U
Roth, S
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 356 : 433 - 437
[10] Hirscher M, 2003, J NANOSCI NANOTECHNO, V3, P3, DOI 10.1166/jnn.200.1723.172

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