Formation of a copper(I) catenate on an electrode surface via S-Au interactions

被引：13

作者：

Kern, JM ^{[1
]}

Raehm, L ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Le Bel, F-67070 Strasbourg, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 01期

关键词：

catenane; gold surface; thiol; 1,10-phenanthroline; Cu(I); molecular motions;

D O I：

10.1016/S1387-1609(99)80037-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A bis-thiol derivative of 2,9-diaryl-1,10-phenanthroline was threaded through a coordinating macrocycle using Cu(I) as a templating agent. This rotaxane adsorbs onto a gold surface, leading to a novel type of catenate, where gold aroma are incorporated within one of the two interlocking rings. The adsorption procedure was monitored by cyclic voltammetry. (C) Academie des sciences/Elsevier, Paris.

引用

页码：41 / 47

页数：7

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