Transition metals in organic synthesis, part 87:: An efficient palladium-catalyzed route to 2-oxygenated and 2,7-dioxygenated carbazole alkaloids -: Total synthesis of 2-methoxy-3-methylcarbazole, glycosinine, clausine L, mukonidine, and clausine V

被引：72

作者：

Forke, Ronny ^{[1
]}

Krahl, Micha P. ^{[1
]}

Daebritz, Frank ^{[1
]}

Jager, Anne ^{[1
]}

Knoelker, Hans-Joachim ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Chem, D-01069 Dresden, Germany

来源：

SYNLETT | 2008年 / 12期

关键词：

alkaloids; antibiotics; catalysis; cyclizations; palladium;

D O I：

10.1055/s-2008-1078508

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Optimization of the palladium(II)-catalyzed oxidative cyclization of N,N-diarylamines opens up the way to an efficient synthesis of 2-oxygenated and 2,7-dioxygenated carbazole alkaloids including 2-methoxy-3-methylcarbazole, glycosinine, clausine L, mukonidine, and clausine V.

引用

页码：1870 / 1876

页数：7

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