trans-tetraaquabis(pyridine-3-carboxylate-κN)-nickel(II)

被引：18

作者：

Batten, SR ^{[1
]}

Harris, AR ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536800018742

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Ni(C6H4NO2)(2) (H2O)(4)], consists of an Ni atom coordinated to two trans pyridinecarboxylate ligands, coordinated through the N atoms, and four water ligands. The Ni atom lies on a site of 2/m symmetry, and the pyridinecarboxylate ligand lies on a mirror plane. Extensive intercomplex hydrogen bonding occurs between the water ligands and the carboxylate groups, resulting in a three-dimensional network.

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页码：M9 / M11

页数：3

相关论文

共 14 条

[1] CRYSTAL STRUCTURE OF COBALT(II) NICOTINATE TETRAHYDRATE - A NON-CLASSICAL ZWITTERION [J].

ANAGNOSTOPOULOS, A ;

DREW, MGB ;

WALTON, RA .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (21) :1241-+

[2]

Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations

[3]

CINGI MB, 1971, GAZZ CHIM ITAL, V101, P455

[4] SOLID-SOLUTIONS OF A JAHN-TELLER COMPOUND IN AN UNDISTORTED HOST .2. HIGH-SPIN, 6-COORDINATE CR-2+ WITHOUT JAHN-TELLER DISTORTION [J].

COTTON, FA ;

FALVELLO, LR ;

OHLHAUSEN, EL ;

MURILLO, CA ;

QUESADA, JF .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1991, 598 (7-8) :53-70

[5] Nanoporous, interpenetrated metal-organic diamondoid networks [J].

Evans, OR ;

Wang, ZY ;

Xiong, RG ;

Foxman, BM ;

Lin, WB .

INORGANIC CHEMISTRY, 1999, 38 (12) :2969-2973

[6]

Evans OR, 1999, ANGEW CHEM INT EDIT, V38, P536, DOI 10.1002/(SICI)1521-3773(19990215)38:4<536::AID-ANIE536>3.0.CO

[7]

2-3

[8] Pillared, 3D metal-organic frameworks with rectangular channels. Synthesis and characterization of coordination polymers based on tricadmium carboxylates [J].

Evans, OR ;

Lin, WB .

INORGANIC CHEMISTRY, 2000, 39 (10) :2189-2198

[9]

Hooft R. W. W., 1998, COLLECT SOFTWARE

[10] Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato}cadmium [J].

Lin, WB ;

Evans, OR ;

Xiong, RG ;

Wang, ZY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (50) :13272-13273