Intergrowth structure of zeolite crystals and pore orientation of individual subunits revealed by electron backscatter diffraction/focused ion beam experiments

被引:63
作者
Stavitski, Eli [3 ]
Drury, Martyn R. [1 ]
de Winter, D. A. Matthijs [2 ]
Kox, Marianne H. F. [3 ]
Weckhuysen, Bert M. [3 ]
机构
[1] Univ Utrecht, Dept Earth Sci, NL-3508 TA Utrecht, Netherlands
[2] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands
[3] Univ Utrecht, Dept Chem, Inorgan Chem & Catalysis Grp, NL-3584 CA Utrecht, Netherlands
关键词
crystal intergrowth; electron diffraction; heterogeneous catalysis; ion beam milling; zeolites;
D O I
10.1002/anie.200801433
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two-component model of coffin-shaped intergrown crystals of zeolite ZSM-5 has been verified by a combination of electron backscattering diffraction and focused ion beam milling (see picture), which respectively revealed the orientation of the channel system in the individual subunits of the crystal and allowed these building blocks to be visualized. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5637 / 5640
页数:4
相关论文
共 34 条
[1]   Silicalite crystal growth investigated by atomic force microscopy [J].
Agger, JR ;
Hanif, N ;
Cundy, CS ;
Wade, AP ;
Dennison, S ;
Rawlinson, PA ;
Anderson, MW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) :830-839
[2]   INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].
CORMA, A .
CHEMICAL REVIEWS, 1995, 95 (03) :559-614
[3]  
DINGERDISSEN U, 2008, HDB HETEROGENEOUS CA, V1, P37
[4]   MICROTEXTURE DETERMINATION BY ELECTRON BACK-SCATTER DIFFRACTION [J].
DINGLEY, DJ ;
RANDLE, V .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (17) :4545-4566
[5]   Interference microscopy investigation of the influence of regular intergrowth effects in MFI-type zeolites on molecular uptake [J].
Geier, O ;
Vasenkov, S ;
Lehmann, E ;
Kärger, J ;
Schemmert, U ;
Rakoczy, RA ;
Weitkamp, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (42) :10217-10222
[6]   THE COMBINATION OF SYNCHROTRON POWDER DIFFRACTION AND HIGH-RESOLUTION SOLID-STATE NMR EXPERIMENTS [J].
GIES, H ;
MARLER, B ;
FYFE, C ;
KOKOTAILO, G ;
FENG, Y ;
COX, DE .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1991, 52 (10) :1235-1241
[7]  
Hagen J., 2006, IND CATALYSIS PRACTI
[8]   SYSTEMATIC INTERGROWTH IN CRYSTALS OF ZSM-5 ZEOLITE [J].
HAY, DG ;
JAEGER, H ;
WILSHIER, KG .
ZEOLITES, 1990, 10 (06) :571-576
[9]   Review - Grain and subgrain characterisation by electron backscatter diffraction [J].
Humphreys, FJ .
JOURNAL OF MATERIALS SCIENCE, 2001, 36 (16) :3833-3854
[10]   Unprecedented insight into diffusion by monitoring the concentration of guest molecules in nanoporous host materials [J].
Kaerger, Joerg ;
Kortunov, Pavel ;
Vasenkov, Sergey ;
Heinke, Lars ;
Shah, Dhananjai R. ;
Rakoczy, Rainer A. ;
Traa, Yvonne ;
Weitkamp, Jens .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (46) :7846-7849