A closed-loop phase diagram in a weakly interacting polyolefin copolymer binary blend system

被引:13
作者
Hu, HQ
Chong, CB
He, AH
Zhang, CG
Fan, GQ
Dong, JY
Han, CC [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
[3] Qingdao Univ Sci & Technol, Coll Polymer Sci & Technol, Qingdao 266042, Peoples R China
关键词
closed-phase loop; PEB; PES; phase diagrams; weakly interacting binary polymer system;
D O I
10.1002/marc.200500182
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理]; 080501 [材料物理与化学]; 081704 [应用化学];
摘要
The phase behavior of poly(ethylene-co-styrene) (PES) and poly(ethylene-co-butene)(PEB) blends has been studied. A closed-loop phase diagram was clearly observed in this weakly interacting system as the styrene content in the PES decrease to about 1 mol-%. At higher styrene contents, the phase loop starts to interplay with the crystallization transformation at lower temperatures.
引用
收藏
页码:973 / 978
页数:6
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