Catalytic transfer reduction of conjugated alkenes and an imine using polymer-supported formates

被引:43
作者
Basu, B [1 ]
Bhuiyan, MH [1 ]
Das, P [1 ]
Hossain, I [1 ]
机构
[1] N Bengal Univ, Dept Chem, Darjeeling 734430, India
关键词
catalytic transfer hydrogenation; polymer-supported formate; palladium acetate; unsaturated alkenes; imines;
D O I
10.1016/j.tetlet.2003.10.019
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An efficient and mild method for catalytic transfer hydrogenation of C=C and C=N double bonds with the aid of resin-supported formate (PSF) as the hydrogen donor and palladium acetate as the catalyst is reported. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:8931 / 8934
页数:4
相关论文
共 22 条
[1]   Microwave-induced organic reaction enhancement (MORE) chemistry. Part 13. Microwave-assisted rapid and simplified hydrogenation [J].
Banik, BK ;
Barakat, KJ ;
Wagle, DR ;
Manhas, MS ;
Bose, AK .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (16) :5746-5753
[2]   Palladium mediated chemoselective reduction of α,β-unsaturated cyano esters with potassium formate [J].
Basu, B ;
Bhuiyan, MMH ;
Jha, S .
SYNTHETIC COMMUNICATIONS, 2003, 33 (02) :291-296
[3]   A simple protocol for direct reductive amination of aldehydes and ketones using potassium formate and catalytic palladium acetate [J].
Basu, B ;
Jha, S ;
Bhuiyan, MH ;
Das, P .
SYNLETT, 2003, (04) :555-557
[4]   Catalytic asymmetric synthesis of bis-armed aromatic amino acid derivatives. Problems related to the synthesis of enantiomerically pure bis-methyl ester of the (S,S)-pyridine-2,6-diyl bis-alanine [J].
Basu, B ;
Frejd, T .
ACTA CHEMICA SCANDINAVICA, 1996, 50 (04) :316-322
[5]   Synthesis of optically active 1,1'-ferrocenylene-bis-alanine carrying four different protecting groups [J].
Basu, B ;
Chattopadhyay, SK ;
Ritzen, A ;
Frejd, T .
TETRAHEDRON-ASYMMETRY, 1997, 8 (11) :1841-1846
[6]   HYDROGEN TRANSFER .1. INTRODUCTORY SURVEY [J].
BRAUDE, EA ;
LINSTEAD, RP .
JOURNAL OF THE CHEMICAL SOCIETY, 1954, (OCT) :3544-3547
[7]  
BRIEGER G, 1974, CHEM REV, V74, P657
[8]  
DELMOND B, 1999, SOLID STATE ORGANOME, P445
[9]   Thermal- and microwave-assisted hydrogenation of electron-deficient alkenes using a polymer-supported hydrogen donor [J].
Desai, B ;
Danks, TN .
TETRAHEDRON LETTERS, 2001, 42 (34) :5963-5965
[10]   REDUCTION OF NITRO-COMPOUNDS [J].
ENTWISTLE, ID ;
JACKSON, AE ;
JOHNSTONE, RAW ;
TELFORD, RP .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (04) :443-444