Glyoxal bis-hydrazones:: a new family of nitrogen ligands for asymmetric catalysis

被引：32

作者：

Lassaletta, JM

Alcarazo, M

Fernández, R

机构：

[1] Inst Invest Quim, Seville 41092, Spain

[2] Univ Seville, Dept Quim Organ, Seville 41071, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 03期

关键词：

D O I：

10.1039/b314249c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The introduction Of C-2-symmetric dialkylamino substructures in chiral non-racemic glyoxal bis-hydrazones such as 9 appears as the key design element for this novel ligand class, as shown in the highly enantioselective copper(II)-catalyzed Diels-Alder reaction.

引用

页码：298 / 299

页数：2

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