Layered double hydroxides: Structure, synthesis, properties and applications.

被引:120
作者
Crepaldi, EL [1 ]
Valim, JB [1 ]
机构
[1] USP, Fac Ciencias & Letras Ribeirao Preto, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil
来源
QUIMICA NOVA | 1998年 / 21卷 / 03期
关键词
layered double hydroxides; anionic clays; hydrotalcite;
D O I
10.1590/S0100-40421998000300011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The layered double hydroxides, known as anionic clays and represented by the general formula [M-1-x(2+), M-x(3+), (OH)(2)](X+) A(x/m)(m)-. nH(2)O, are a group of materials which are of much interest currently. They present a variety of potential applications as adsorbents, catalysts and catalyst support, ion-exchangers, antacids and as a polymer stabilizer. It is possible to obtain a broad variety of layered double hydroxides (LDHs), depending on the identity and ratio of the cations M2+ and M3+, as well as the interlamelar anion. The aim of this review is to give out some information about this class of materials, concerning to the synthesis, characterization, properties and applications.
引用
收藏
页码:300 / 311
页数:12
相关论文
共 81 条
[1]   CRYSTAL STRUCTURE OF PYROAURITE [J].
ALLMANN, R .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :972-&
[2]   Calcined hydrotalcites for the catalytic decomposition of N2O in simulated process streams [J].
Armor, JN ;
Braymer, TA ;
Farris, TS ;
Li, Y ;
Petrocelli, FP ;
Weist, EL ;
Kannan, S ;
Swamy, CS .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1996, 7 (3-4) :397-406
[3]   NOVEL HETEROGENEOUS ROUTE FOR THE COUPLING OF PHENYLETHYNE BY A CATALYST DERIVED FROM CU-MG-AL HYDROTALCITE [J].
AUER, SM ;
SCHNEIDER, M ;
BAIKER, A .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (20) :2057-2058
[4]  
BARLOY L, 1992, NEW J CHEM, V16, P71
[5]   ACID-BASE TESTING OF CATALYSTS USING 1-BUTENE ISOMERIZATION AS TEST REACTION [J].
BERES, A ;
HANNUS, I ;
KIRICSI, I .
REACTION KINETICS AND CATALYSIS LETTERS, 1995, 56 (01) :55-61
[6]  
BISH DL, 1980, B MINERAL, V103, P170
[7]  
BISH DL, 1977, AM MINERAL, V62, P458
[8]   Influence of the acid-base character of supported vanadium catalysts on their catalytic properties for the oxidative dehydrogenation of n-butane [J].
Blasco, T ;
Nieto, JML ;
Dejoz, A ;
Vazquez, MI .
JOURNAL OF CATALYSIS, 1995, 157 (02) :271-282
[9]   [ZN2CR(OH)6]X.2H2O, NEW LAYER COMPOUNDS CAPABLE OF ANION-EXCHANGE AND INTRACRYSTALLINE SWELLING [J].
BOEHM, HP ;
STEINLE, J ;
VIEWEGER, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (04) :265-266
[10]  
BRINDLEY GW, 1979, AM MINERAL, V64, P836