Electrochemical synthesis: a novel technique for processing multi-functional coatings

被引:60
作者
Iroh, JO [1 ]
Zhu, YR
Shah, K
Levine, K
Rajagopalan, RR
Uyar, T
Donley, M
Mantz, R
Johnson, J
Voevodin, NN
Balbyshev, VN
Khramovb, AN
机构
[1] Univ Cincinnati, Dept Mat Sci & Engn, Cincinnati, OH 45221 USA
[2] Universal Technol Corp, Dayton, OH 45432 USA
[3] Univ Dayton, Res Inst, Dayton, OH 45469 USA
[4] USAF, Res Lab, Nonmetall Div, Mfg & Mat Directorat, Wright Patterson AFB, OH 45433 USA
关键词
polyaniline (PANi); polypyrrole (PPy); PPy-PANi composite coatings; PPy/PPy-PANi bi-layer coatings; electrochemical synthesis;
D O I
10.1016/j.porgcoat.2003.07.006
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Electrochemical synthesis is a powerful tool for surface modification, substrate cleaning and formulation of thin films and bulk materials. It is especially suited for surface modification of fibers, metals and films. In the past decade electrochemical method has become the preferred technique for in situ passivation, and coating of commodity metals such as aluminum, zinc, copper and steel. We have successfully synthesized different kinds of conducting polymers, including polypyrrole (PPy)-polyaniline (PANi) composites. The processability and corrosion performance of PPy/PANi, composite coatings are significantly better than those for either PPy or PANi, coatings. In this paper, we will discuss the use of electrochemical technique in the synthesis and characterization of multi-functional corrosion resistant conducting polymer coatings for aerospace and automotive applications. (C) 2003 Published by Elsevier B.V.
引用
收藏
页码:365 / 375
页数:11
相关论文
共 20 条
[1]   FILMFORMING ELECTROPOLYMERIZATION OF PYRROLE ON IRON IN AQUEOUS OXALIC-ACID [J].
BECK, F ;
MICHAELIS, R ;
SCHLOTEN, F ;
ZINGER, B .
ELECTROCHIMICA ACTA, 1994, 39 (02) :229-234
[2]  
BECK F, 1992, J COATING TECHNOL, V64, P59
[3]   Electrosynthesis of adherent polyaniline films on iron and mild steel in aqueous oxalic acid medium [J].
Camalet, JL ;
Lacroix, JC ;
Aeiyach, S ;
Chane-Ching, K ;
Lacaze, PC .
SYNTHETIC METALS, 1998, 93 (02) :133-142
[4]  
CITROEN PSA, 1992, Patent No. 9092
[5]   ELECTRODEPOSITION OF N-SUBSTITUTED POLYPYRROLES ON IRON AND THE CIPL STRATEGY [J].
HAASE, V ;
BECK, F .
ELECTROCHIMICA ACTA, 1994, 39 (8-9) :1195-1205
[6]  
Iroh JO, 1999, J APPL POLYM SCI, V71, P2075, DOI 10.1002/(SICI)1097-4628(19990321)71:12<2075::AID-APP18>3.0.CO
[7]  
2-Q
[8]   The kinetic behavior for the electrochemical polymerization of aniline in aqueous solution [J].
Mu, SL ;
Chen, CX ;
Wang, JM .
SYNTHETIC METALS, 1997, 88 (03) :249-254
[9]   Detailed characterization of potentiostatic current transients with 2D-2D and 2D-3D nucleation transitions [J].
Palomar-Pardave, M ;
Miranda-Hernandez, M ;
Gonzalez, I ;
Batina, N .
SURFACE SCIENCE, 1998, 399 (01) :80-95
[10]   Formation of conducting polyaniline coatings on iron surfaces by electropolymerization of aniline in aqueous solutions [J].
Sazou, D ;
Georgolios, C .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 429 (1-2) :81-93