First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective

被引：136

作者：

Chakraborty, Sumit ^{[1
]}

Guan, Hairong ^{[1
]}

机构：

[1] Univ Cincinnati, Dept Chem, Dr Hairong Guans Res Grp, Cincinnati, OH 45221 USA

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 32期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE; P-N-N; LIGAND BIFUNCTIONAL CATALYSIS; ISOTOPE EFFECT EVIDENCE; HOMOGENEOUS CATALYSIS; DIHYDROGEN COMPLEXES; ENANTIOSELECTIVE HYDROSILYLATION; IRON(II) COMPLEXES; DONOR ABILITIES;

D O I：

10.1039/c002942d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of first-row transition metals lot the catalytic reduction of carbonyl functionalities has become increasingly important in homogeneous catalysis This Perspective examines the mechanistic aspects of these reduction reactions, with a focus on various interactions between metal complexes and substrates Four different types of catalytic pathways. namely catalysis with dihydride (or dihydrogen) complexes. catalysis with monohydride complexes. metal-ligand bifunctional catalysis. and catalysis involving ionic mechanisms, are discussed with recent examples highlighted

引用

页码：7427 / 7436

页数：10

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