Synthesis and characterization of (arene)ruthenium(II)poly(pyrazolyl)borate and poly(pyrazolyl)methane complexes

被引：44

作者：

Bhambri, S ^{[1
]}

Tocher, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 16期

关键词：

D O I：

10.1016/0277-5387(95)00548-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A range of compounds of the formulae [Ru(eta(6)-arene) (HBPz(3))][PF6] and [Ru(eta(6)- arene) (HCPz(3))][PF6](2) (Pz = pyrazolyl) has been prepared by a modification of the literature method. These compounds have all been characterized by H-1 and C-13 NMR spectroscopy and the X-ray crystal structures of [Ru(eta(6)-p-cymene) (HBPz(3))][PF6] and [RU(eta(6)-p-cymene)(HCPz(3))] [PF6](2) have been determined. The previously elusive compound [Ru(eta(6)-C6H6) (HB{3,5-Me(2)Pz}(3))][PF6] was observed for the first time. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2763 / 2770

页数：8

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