Tailoring photochromic performance of polymer-dye conjugates using living radical polymerization (ATRP)

被引:15
作者
Such, GK
Evans, RA
Davis, TP
机构
[1] CSIRO, Mol Sci, Clayton, Vic 3169, Australia
[2] CRC Polymers, Notting Hill, Australia
[3] Univ New S Wales, Sch Chem Engn & Ind Chem, CAMD, Sydney, NSW, Australia
关键词
ATR; living radical polymerisation; photocbromism; spirooxazine;
D O I
10.1080/15421400590946505
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photochromic performance of polymer-dye conjugates was successfully tailored using the living radical polymerization technique ATRP. ATRP allowed the synthesis of photochromic dye-polymer conjugates consisting of polymer of defined chain length and polydispersity with a single photochromic dye attached at one end. Control over the photochromic switching speed was achieved solely thorough choice of the chain length of the polymer conjugate.
引用
收藏
页码:273 / 279
页数:7
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