Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

被引:25
作者
Burrows, Andrew D. [1 ]
Mahon, Mary F. [1 ]
Wong, Claudia T. F. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源
CRYSTENGCOMM | 2008年 / 10卷 / 05期
关键词
D O I
10.1039/b718961c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
[Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)(2)}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.
引用
收藏
页码:487 / 489
页数:3
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