Surface chemistry, pore sizes and adsorption properties of activated carbon fibers and precursors treated with ammonia

被引：420

作者：

Mangun, CL ^{[1
]}

Benak, KR ^{[1
]}

Economy, J ^{[1
]}

Foster, KL ^{[1
]}

机构：

[1] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA

来源：

CARBON | 2001年 / 39卷 / 12期

基金：

美国能源部; 美国国家科学基金会;

关键词：

carbon fibers; carbon precursor; activation; adsorption; surface properties;

D O I：

10.1016/S0008-6223(00)00319-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of activated carbon fibers (ACFs) were produced by treatment with ammonia to yield a basic surface. The micropore sizes of these chemically modified fibers were determined with nitrogen adsorption experiments and they were shown to increase with increasing activation time and temperature. The types of groups present were analyzed by Fourier transform infrared spectroscopy (FTIR). X-ray photoelectron spectroscopy (XPS), and temperature programmed desorption (TPD). The adsorption isotherms of an acidic gas (HCl) show a great improvement in capacity over an untreated acidic fiber. The adsorption is completely reversible and must therefore involve enhanced physical adsorption instead of chemisorption. This demonstrates that ACFs can be tailored to selectively remove a specific contaminant based on the chemical modification of their pore surfaces. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1809 / 1820

页数：12

共 17 条

[1] Effect of electrolytic oxidation upon the surface chemistry of type a carbon fibres .3. Chemical state, source and location of surface nitrogen [J].

Alexander, MR ;

Jones, FR .

CARBON, 1996, 34 (09) :1093-1102

[2]

Chastain J., 1995, HDB PHOTOELECTRON SP

[3] Elucidating the porous structure of activated carbon fibers using direct and indirect methods [J].

Daley, MA ;

Tandon, D ;

Economy, J ;

Hippo, EJ .

CARBON, 1996, 34 (10) :1191-1200

[4] XPS DETERMINATION OF OXYGEN-CONTAINING FUNCTIONAL-GROUPS ON CARBON-FIBER SURFACES AND THE CLEANING OF THESE SURFACES [J].

DESIMONI, E ;

CASELLA, GI ;

MORONE, A ;

SALVI, AM .

SURFACE AND INTERFACE ANALYSIS, 1990, 15 (10) :627-634

[5] HOMOGENEOUS AND HETEROGENEOUS MICROPORE STRUCTURES IN CARBONACEOUS ADSORBENTS [J].

DUBININ, MM ;

STOECKLI, HF .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 75 (01) :34-42

[6]

ECONOMY J, 1992, CHEMTECH, V22, P597

[7] A DRIFTS STUDY OF THE FORMATION OF SURFACE GROUPS ON CARBON BY OXIDATION [J].

FANNING, PE ;

VANNICE, MA .

CARBON, 1993, 31 (05) :721-730

[8] XPS OF NITROGEN-CONTAINING FUNCTIONAL-GROUPS ON ACTIVATED CARBON [J].

JANSEN, RJJ ;

VANBEKKUM, H .

CARBON, 1995, 33 (08) :1021-1027

[9] THE EFFECT OF LOW-POWER PLASMAS ON CARBON-FIBER SURFACES [J].

JONES, C ;

SAMMANN, E .

CARBON, 1990, 28 (04) :509-514

[10]

Lin R.Y., 1973, APPL POLYM S, V21, P143

← 1 2 →