Excited-state behavior of some all-trans-α,ω-dithienylpolyenes

被引:45
作者
Bartocci, G [1 ]
Spalletti, A [1 ]
Becker, RS [1 ]
Elisei, F [1 ]
Floridi, S [1 ]
Mazzucato, U [1 ]
机构
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
关键词
D O I
10.1021/ja983250c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The photophysics and photochemistry of all-trans-alpha,omega-di(2-thienyl)polyenes (with chain length n = 2, 3, 4) and alpha,omega-di(3-thienyl)polyenes (with n = 3, 4) have been extensively studied by stationary and pulsed spectrometry. Fluorometric and laser flash techniques were used to measure the quantum yields and lifetimes of the lowest excited states of singlet and tripler multiplicity in nonpolar and polar solvents at different temperatures. The trans-cis photoisomerization was also investigated, at least for the shorter oligomers. The kinetic parameters of the radiative, nonradiative, and reactive relaxation pathways were evaluated and discussed by comparison with the parent compound having n = 1 (trans-1,2-dithienylethene) and the better known alpha,omega-diphenylpolyenes.
引用
收藏
页码:1065 / 1075
页数:11
相关论文
共 46 条
[1]   FLUORESCENCE OF DPH DERIVATIVES - EVIDENCE FOR EMISSION FROM S2 AND S1 EXCITED-STATES [J].
ALFORD, PC ;
PALMER, TF .
CHEMICAL PHYSICS LETTERS, 1982, 86 (03) :248-253
[2]   TEMPERATURE EFFECTS ON FLUORESCENCE IN DIPHENYLPOLYENE DERIVATIVES - STRUCTURE-DEPENDENT AND SUBSTITUENT-DEPENDENT CHANGES IN MECHANISMS AND RATES FOR NONRADIATIVE DECAY [J].
ALLEN, MT ;
MIOLA, L ;
WHITTEN, DG .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (24) :6099-6102
[3]   THE PHOTOPHYSICS AND PHOTOCHEMISTRY OF ALPHA,OMEGA-DIPHENYLPOLYENE SINGLET-STATES [J].
ALLEN, MT ;
WHITTEN, DG .
CHEMICAL REVIEWS, 1989, 89 (08) :1691-1702
[4]   THE 3-COMPONENT FLUORESCENCE EMISSION OF TRANS-2-STYRYLANTHRACENE IN FLUID SOLUTION - THE IMPLICATION OF AN UPPER EXCITED SINGLET-STATE [J].
BARTOCCI, G ;
MAZZUCATO, U ;
SPALLETTI, A ;
ELISEI, F .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (03) :413-418
[5]   PHOTOPHYSICAL AND THEORETICAL-STUDIES OF PHOTOISOMERISM AND ROTAMERISM OF TRANS-STYRYLPHENANTHRENES [J].
BARTOCCI, G ;
MASETTI, F ;
MAZZUCATO, U ;
SPALLETTI, A ;
BARALDI, I ;
MOMICCHIOLI, F .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (18) :4733-4743
[6]  
Bartocci G, 1995, RECL TRAV CHIM PAY B, V114, P459
[7]   2-PHOTON SPECTROSCOPY OF DIPHENYLBUTADIENE - THE NATURE OF THE LOWEST-LYING 1AG STAR-PI-PI-STAR STATE [J].
BENNETT, JA ;
BIRGE, RR .
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (09) :4234-4246
[8]   TRIPLET-STATE OF 1,6-DIPHENYL-1,3,5-HEXATRIENE AND 1,8-DIPHENYL-1,3,5,7-OCTATETRAENE [J].
BENSASSON, R ;
LAND, EJ ;
LAFFERTY, J ;
SINCLAIR, RS ;
TRUSCOTT, TG .
CHEMICAL PHYSICS LETTERS, 1976, 41 (02) :333-335
[9]  
BENSASSON RV, 1993, EXCITED STATES FREE, P201
[10]  
Birks, 1970, PHOTOPHYSICS AROMATI, P88