High catalytic activity of nanostructured Pd thin films electrochemically deposited on polycrystalline Pt and Au substrates towards electro-oxidation of methanol

Nanostructured Pd thin films are directly formed on polycrystalline Pt and Au substrates in the absence of hard and soft templates by using a cyclic potential sweep technique, which is confirmed by both SEM observation and their unusual cyclic voltammetric characteristics in H2SO4 solution. Interestingly, the bimetallic electrodes obtained after the deposition of ultrathin Pd films onto Pt and Au substrates display much higher catalytic activity towards the electro-oxidation of methanol than the bulk Pt electrode. Besides, it is found that the foreign metal substrate has great influence on the electro-catalytic behavior of the Pd films. (c) 2007 Elsevier B.V. All rights reserved.