Environmentally friendly synthesis of organic-soluble silver nanoparticles for printed electronics

被引:69
作者
Lee, Kwi Jong [1 ]
Jun, Byung Ho [1 ]
Choi, Junrak [1 ]
Lee, Young Il [1 ]
Joung, Jaewoo [1 ]
Oh, Yong Soo [1 ]
机构
[1] Samsung Electromech, eMD Ctr, Suwon 443743, Kyunggi Do, South Korea
关键词
D O I
10.1088/0957-4484/18/33/335601
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, we attempted to synthesize organic-soluble silver nanoparticles in the concentrated organic phase with an environmentally friendly method. The fully organic phase system contains silver acetate as a silver precursor, oleic acid as both a medium and a capping molecule, and tin acetate as a reducing agent. Monodisperse silver nanoparticles with average diameters of ca. 5 nm can be easily synthesized at large scale. Only a small usage of tin acetate (< 0.05 eq. mol) resulted in a high synthesis yield (> 90%). Also, it was investigated that the residual tin atom does not exist in the synthesized silver nanoparticles. This implied that tin acetate acts as a reducing catalyst.
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页数:5
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